Enantioselective Intramolecular Cyclopropanation Catalyzed by Semicorrin-Copper Complexes
- 1 June 1995
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1995 (SI) , 491-492
- https://doi.org/10.1055/s-1995-5283
Abstract
Chiral semicorrin-copper complexes are efficient enantioselective catalysts for intramolecular cyclopropanation reactions of diazomethyl alkenyl ketones leading to bicyclo[3.1.0]hexan-2-ones (up to 85% ee) and bicyclo[4.1.0]heptan-2-ones (up to 95% ee).Keywords
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