p-Xylene autoxidation studies. Oxidation of cobalt(II) and manganese(II) acetates by peracids
- 1 January 1979
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 536-537
- https://doi.org/10.1039/c39790000536
Abstract
The stoicheiometric oxidations of both cobalt(II) and manganese(II) acetates in aqueous acetic acid by m-chloroperbenzoic acid are non-free radical processes, the former proceeding via a peracid·CoII 2 complex to give an active form of cobalt(III) which rearranges to a more stable form, and the latter proceeding in an autocatalytic fashion via a peracid·MnIII 2 complex to give, in the presence of excess peracid, manganese(IV).Keywords
This publication has 0 references indexed in Scilit: