Radical Cation Salts - A New Family of Organic Metals
- 1 May 1982
- journal article
- Published by Taylor & Francis in Molecular Crystals and Liquid Crystals
- Vol. 86 (1) , 103-110
- https://doi.org/10.1080/00268948208073673
Abstract
Stable radical cations of arenes can be generated by anodic oxidation and can be separated at the anode in the presence of suitable anions as radical cation salts [ary12]†X in the form of shiny black crystals. Crystal structures and phase transitions in fluoranthenyl radical cation salts, a new family of organic conductors, are reported. The metal to semiconductor transition which is observed seems to be related to a distortion of the stacks of aromatic molecules perpendicular to the stacking direction.Keywords
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