Dynamic-coupling approach to the optical activity of the 260 nm transition of chiral thiirans
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 398-399
- https://doi.org/10.1039/c39740000398
Abstract
The 260 nm optically active transition of chiral thiirans (episulphides) is rationalized in terms of the dynamic coupling mechanism; the transition charge distribution on the carbon atoms, derived mainly from two-center overlap integrals between sulphur and carbon, plays an important role.Keywords
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