Synthesis and crystal structure of the mixed alkali metal imide Li_{4 -x}Na_{2 +x}[NC(Ph)Bu^t]₆: three (metal–nitrogen)₂ring dimers in a triple-layered stack

Abstract

The first uncomplexed mixed alkali metal molecular species to be synthesised and structurally characterised, Li_{4 –x}Na₂ ₊ _x[NC(Ph)Bu^t]₆, has been shown by X-ray diffraction to exist as a complicated series of discrete isostructural molecules, each with six metal centres, arranged in a triple-stack of (metal–nitrogen)₂ cyclic rings.

Keywords

STRUCTURALLY
NITROGEN
ALKALI
MIXED
IMIDE
CHARACTERISED
CRYSTAL
UNCOMPLEXED

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Synthesis and crystal structure of the mixed alkali metal imide Li4 -xNa2 +x[NC(Ph)But]6: three (metal–nitrogen)2ring dimers in a triple-layered stack

Abstract

Keywords

Synthesis and crystal structure of the mixed alkali metal imide Li_{4 -x}Na_{2 +x}[NC(Ph)Bu^t]₆: three (metal–nitrogen)₂ring dimers in a triple-layered stack