Valence Force Field Calculations for Octahedral Anions
- 1 March 1971
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 49 (5) , 816-819
- https://doi.org/10.1139/v71-138
Abstract
Vibrational force constants for the octahedral anion AsF6−, SbF6−, SnF62−, and SnCl62− in the corresponding potassium salts are calculated using a simple valence force field treatment, with the intention of obtaining better agreement with recently reassigned bending modes in these compounds and to arrive at improved values for the inactive mode ν6[F2u].Keywords
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