Albumin-Conjugated Corrole Metal Complexes: Extremely Simple Yet Very Efficient Biomimetic Oxidation Systems
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- 11 February 2005
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 127 (9) , 2883-2887
- https://doi.org/10.1021/ja045372c
Abstract
An extremely simple biomimetic oxidation system, consisting of mixing metal complexes of amphiphilic corroles with serum albumins, utilizes hydrogen peroxide for asymmetric sulfoxidation in up to 74% ee. The albumin-conjugated manganese corroles also display catalase-like activity, and mechanistic evidence points toward oxidant-coordinated manganese(III) as the prime reaction intermediate.Keywords
This publication has 27 references indexed in Scilit:
- Hydroperoxoferric heme intermediate as a second electrophilic oxidant in cytochrome P450-catalyzed reactionsJBIC Journal of Biological Inorganic Chemistry, 2004
- Recent Developments in the Synthesis and Utilization of Chiral SulfoxidesChemical Reviews, 2003
- Introduction of P450, Peroxidase, and Catalase Activities into Myoglobin by Site-Directed Mutagenesis: Diverse Reactivities of Compound IBulletin of the Chemical Society of Japan, 2003
- Preparation and Initial Characterization of the Compound I, II, and III States of Iron Methylchlorin-Reconstituted Horseradish Peroxidase and Myoglobin: Models for Key Intermediates in Iron Chlorin EnzymesBiochemical and Biophysical Research Communications, 2000
- Epoxidation Catalysis by a Manganese Corrole and Isolation of an Oxomanganese(V) CorrolePublished by Wiley ,2000
- Dual Role of Pyridine N-Oxides in Ruthenium Porphyrin-Catalyzed Asymmetric Epoxidation of OlefinsInorganic Chemistry, 1999
- Conversion of Myoglobin into a Highly Stereo- specific Peroxygenase by the L29H/H64L MutationJournal of the American Chemical Society, 1996
- Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavageChemical Reviews, 1992
- Enantio and diastereoselectivity in the periodate oxidation of sulfides catalyzed by bovine serum albumin. 2The Journal of Organic Chemistry, 1986
- Synthesis, characterization, and reaction chemistry of a bis(iodosylbenzene)metalloporphyrin complex, [PhI(OAc)O]2MnIVTPP. A complex possessing a five-electron oxidation capabilityJournal of the American Chemical Society, 1983