Some new synthetic approaches to graphite–fluorine chemistry
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 12,p. 1268-1273
- https://doi.org/10.1039/dt9740001268
Abstract
New methods for synthesising poly(carbon monofluoride)(CFx)n and tetracarbon monofluoride C4F are reported. Pyrolytic graphite has been fluorinated and a new compound, graphite oxyfluoride, has been prepared. Poly(carbon monofluoride) has been prepared in a flow reactor, in a fluidized-bed reactor, and in a high-pressure bomb reactor and tetracarbon monofluoride has been prepared by a high-pressure bomb technique. Some new structural data are presented for poly(carbon monofluoride). Recently, poly(carbon monofluoride) has been found to have a high potential as a solid lubricant and as a cathode material in high-energy batteries.Keywords
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