Thermodynamic Theory of the Pair Correlation Function
- 1 May 1961
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 34 (5) , 1471-1475
- https://doi.org/10.1063/1.1701031
Abstract
The thermodynamic description of inhomogeneous systems is adapted to a determination of the pair correlation function. The method is most effective for describing the correlation behavior near a critical point. The critical‐point behavior is investigated for a simple model fluid of the van der Waal's type. A novel optical scattering phenomenon is predicted for the interface between two equilibrium phases for temperatures below but very near to the critical temperature. The effect of inclusions on critical point phenomena is noted.Keywords
This publication has 4 references indexed in Scilit:
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- Thermodynamics of Inhomogeneous Systems. IIPhysical Review B, 1959
- Thermodynamics of Inhomogeneous SystemsPhysical Review B, 1959
- Free Energy of a Nonuniform System. I. Interfacial Free EnergyThe Journal of Chemical Physics, 1958