Preparation of Hyperbranched Polymethacrylates by Self-Condensing Group Transfer Polymerization
- 1 December 1997
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 26 (12) , 1245-1246
- https://doi.org/10.1246/cl.1997.1245
Abstract
Hyperbranched polymethacrylates were synthesized by group transfer self-condensation polymerization of 2-(2-methyl-1-triethylsiloxy-1-propenyloxy)ethyl methacrylate. The hyper-branched structure of the polymer was characterized by 13C NMR spectroscopy. The extent of the branching depended on the nucleophilic catalysts used for activation of the monomer.Keywords
This publication has 12 references indexed in Scilit:
- Synthesis of Branched and Hyperbranched PolystyrenesMacromolecules, 1996
- Preparation of Hyperbranched and Star Polymers by a "Living", Self-Condensing Free Radical PolymerizationJournal of the American Chemical Society, 1995
- Functional Polymers and Dendrimers: Reactivity, Molecular Architecture, and Interfacial EnergyScience, 1994
- Multibranching polymerization: palladium-catalyzed ring-opening polymerization of cyclic carbamate to produce hyperbranched dendritic polyamineMacromolecules, 1992
- Mechanistic studies of group transfer polymerization. Silyl group exchange studiesMacromolecules, 1992
- Starburst Dendrimers: Molecular‐Level Control of Size, Shape, Surface Chemistry, Topology, and Flexibility from Atoms to Macroscopic MatterAngewandte Chemie International Edition in English, 1990
- Termination in group-transfer polymerizationMacromolecules, 1989
- Group-transfer polymerization. 1. A new concept for addition polymerization with organosilicon initiatorsJournal of the American Chemical Society, 1983
- Hydrosilylation of α,β-unsaturated nitriles and esters catalyzed by tris (triphenylphosphine)chlororhodiumJournal of Organometallic Chemistry, 1976
- Hydrosilation of .ALPHA.,.BETA.-unsaturated esters.CHEMICAL & PHARMACEUTICAL BULLETIN, 1974