A USEFUL METHOD FOR SELECTIVE ACYLATION OF ALCOHOLS USING 2,2′-BIPYRIDYL-6-YL CARBOXYLATE AND CESIUM FLUORIDE
- 5 May 1980
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 9 (5) , 563-566
- https://doi.org/10.1246/cl.1980.563
Abstract
Primary and secondary alcohols are acylated under mild conditions by the use of 2,2′-bipyridyl-6-yl carboxylates and cesium fluoride. Furthermore, the reaction is successfully applied to selective acylation of a primary carbinol group of diols containing primary and secondary carbinol groups or exclusive O-acylation of aromatic amino alcohols.Keywords
This publication has 3 references indexed in Scilit:
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- Hydrogen bonding in organic synthesis. 3. Hydrogen bond assisted reactions of cyclic organic hydrogen bond electron acceptors with halogenoalkanes in the presence of potassium fluorideJournal of the American Chemical Society, 1977
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