A New Carbacyclin Synthesis
- 1 January 1986
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1986 (01) , 41-42
- https://doi.org/10.1055/s-1986-31469
Abstract
After opening of substituted Corey lactones by alkali, acidification and Jones oxidation to the γ-keto acids, reaction with triphenyl-(phenyliminovinylidene)-phosphorane afforded in 50% overall yield the corresponding unsaturated bicyclo[3.3.0]octane-1-one derivatives, which could be readily reduced to the saturated bicyclic ketones.Keywords
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