Notes. The easy catalytic reduction of HClO4, HNO3, and H5IO6 by CO in the presence of [Pd3(O2CMe)6]
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 9,p. 1971-1973
- https://doi.org/10.1039/dt9850001971
Abstract
The reduction of HClO4 to HCl by CO, catalysed in acetic acid by [Pd3(O2CMe)6], is reported together with the parallel formation of either [{Pd(CO)Cl}n] or β-PdCl2 according to the reaction conditions. Under similar conditions HNO3 is reduced first to NO2 and then to NO; the known compound [Pd4(O2CMe)4(CO)4]·2MeCO2H is the final product. With H5IO6 only insoluble PdI2 is obtained under each reaction condition, corresponding to an easy reduction by CO of H5IO6.Keywords
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