Synthesis and thermal reactions of perfluoroalkylsulphonyl substituted ylides
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 470-471
- https://doi.org/10.1039/c39910000470
Abstract
The synthesis of several perfluoroalkylsulphonyl substituted ylides is described; thermal decomposition of the phenyliodonio(cyanononafluorobutylsulphonyl)methanide 3a in cyclohexene yields the bicyclo[4.1.0]heptane derivative, while the phenyliodoniobis(nonafluorobutylsulphonyl)methanide 3c gives an insertion reaction.Keywords
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