Spectral study of the phosphorus glow
- 15 December 1970
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Physics
- Vol. 48 (24) , 2991-2995
- https://doi.org/10.1139/p70-371
Abstract
A bright flame produced by the reaction of atomic oxygen with white phosphorus has been developed. In addition to a visible continuum, the emission consists of several transitions of PO and the A1Πg–X1Σg+ transition of P2. Atomic oxygen and a third body such as H2O or H2 is found essential for the production of discrete bands. Pressure effects on the intensity of the β bands of PO indicate the presence of a heterogeneous perturbation in the B2Σ (ν = 7) level by a 2Πr state.Keywords
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