The effect of the large hydrogen dissociation activation energy on an equilibrium-broadened hydrogen-oxygen diffusion flame
- 11 November 1969
- journal article
- Published by The Royal Society in Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
- Vol. 313 (1514) , 433-443
- https://doi.org/10.1098/rspa.1969.0203
Abstract
The structure of a hydrogen-oxygen diffusion flame under equilibrium conditions is dominated by the influence of the equilibrium constant for the hydrogen dissociation-recombination reaction. An attempt to continue a previous solution, which used the method of matched asymptotic expansions, to higher orders of approximation led to difficulties of a numerical kind as a result of the large rate-of-change of this equilibrium constant with temperature. It is shown how the matter can be resolved by using the asymptotic expansion method with the small parameter (reciprocal of the equilibrium constant) treated as a function of temperature; the solutions follow from a simple iterative procedure.Keywords
This publication has 2 references indexed in Scilit:
- Reaction-broadening in a hydrogen─oxygen diffusion flameProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1969
- On the structure of a hydrogen-oxygen diffusion flameProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1968