Synthesis of N,N-dialkylcarbamato complexes of Group 4 metals (Ti, Zr, Hf) by the metal chloride–NHR2–CO2system (R = Et or Pri): crystal and molecular structure of [Hf(O2CNPri2)4]
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. S,p. 693-698
- https://doi.org/10.1039/dt9910000693
Abstract
The compounds [M(O2CNR2)4](M = Ti, Zr or Hf; R = Et or Pri) have been prepared by treating the corresponding metal tetrachloride with CO2–NHR2 in toluene. The structure of [Hf(O2CNPri 2)4] has been solved by X-ray diffraction methods. Crystal data: monoclinic, space group P21/c, a= 12.756(3), b= 22.131(9), c= 14.548(5)Å, β= 113.03(2)° and Z= 4. It consists of monomeric units, the hafnium atom being surrounded by the eight oxygen atoms of the four N,N-diisopropylcarbamato groups in a slightly distorted dodecahedral arrangement. By reaction with anhydrous hydrogen halides HX (X = Cl, Br or I) the hexahalogenometalate(IV) anions, [MX6]2–, as the diethylammonium derivatives, have been obtained in high yields. The redox reaction between [Ti(O2CNEt2)4] and [V(η-C5Me5)2] gives the titanium(III) and vanadium(III) complexes [{Ti(O2CNEt2)3}n] and [V(η-C5Me5)2(O2CNEt2)], respectively.Keywords
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