Cationic Pentafluorophenyl Complexes of Palladium(II)
- 1 January 1974
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 4 (2) , 157-165
- https://doi.org/10.1080/00945717408069646
Abstract
The complex O3ClOPd(C6F5)(PPh3)2 has proved to be a fairly effective intermediate for the synthesis of cationic derivatives of Pd(II), since the perchlorato ligand shows a poor coordination capacity and is therefore easily displaced by neutral ligands. In this way cationic complexes of the [LPd(C6F5)(PPh3)2]ClO4 type have been prepared, where L[dbnd]PPh3, PEt3, PBu3, C5H5N, AsPh3, HN(CH2-CH2-CH3)2, H2O, O2NCH3, ONC5H4.C6H5, OPPh3 or SPPh3.Keywords
This publication has 4 references indexed in Scilit:
- Two New Ways for the Synthesis of Pentafluorophenyl-Gold(III) ComplexesSynthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 1973
- The use of conductivity measurements in organic solvents for the characterisation of coordination compoundsCoordination Chemistry Reviews, 1971
- Études de composés d'addition des acides de LEWIS. XV. Recherches cristallographiques sur les composés formés par des nitrodérivés avec le chlorure d'aluminiumHelvetica Chimica Acta, 1961
- Infrarotspektroskopische Untersuchungen an einigen Pyridinen und deren N-Oxyde.Zeitschrift für Physikalische Chemie, 1955