Osmabenzenes from the Reactions of HC≡CCH(OH)C≡CH with OsX2(PPh3)3 (X = Cl, Br)
- 14 May 2004
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 126 (22) , 6862-6863
- https://doi.org/10.1021/ja0486871
Abstract
Treatment of OsX2(PPh3)3 (X = Cl, Br) with HC⋮CCH(OH)C⋮CH in THF produces OsX2(CHC(PPh3)CH(OH)C⋮CH)(PPh3)2, which reacts with PPh3 to give osmabenzenes [Os(CHC(PPh3)CHC(PPh3)CH)X2(PPh3)2]+.Keywords
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