Analytical Hartree-Fock Self-Consistent-Field Wave Functions for some $1 s^{1} 2 s^{1} 2 p^{6}$ Configurations

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15 November 1961

journal article
research article
Published by American Physical Society (APS) in Physical Review B

Vol. 124 (4) , 1283-1289
https://doi.org/10.1103/physrev.124.1283

Abstract

Analytical Hartree-Fock self-consistent-field solutions have been obtained by matrix methods for the ten-electron systems

F^{-}

, Ne, and

{Na}^{+}

. In addition, solutions have been obtained for the

F^{-}

and

{Na}^{+}

ions in the presence of a superposed potential sphere. Tables of the two goodness functions,

f (r) = F R - ε R

and

g (r) = \frac{FR}{ε R}

, and expectation values of

r_{i}

and

{r_{i}}^{2}

are given. The diamagnetic susceptibility has been calculated for all the systems reported.

Keywords

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