Reactivity of the perhalogenoalkanes CF2BrX (X = Cl, Br) with nucleophiles. Part 4. Condensation with carbanions
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 1063-1065
- https://doi.org/10.1039/p19820001063
Abstract
The condensation of CF2BrX (X = Cl, Br) with different carbanions is described. CF2BrX reacts with lithium acetylides and with substituted, active methylene compounds. The limits of reactivity of this reagent as well as the mechanism involved in the condensation are examined.Keywords
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