Novel insertion of [M(PR₃)₂] fragments (M = Pd, Pt) into the strained phosphorus–carbon bond of the phosphirene complex [W(CO)₅(PhPC₂Ph₂)]. Crystal and molecular structure of [PtW(CO)₅(PEt₃)₂(PhPC₂Ph₂)]

1 January 1986

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 10,p. 762-763
https://doi.org/10.1039/c39860000762

Abstract

The striain phosphirene ring in [W(CO)₅(PhPC₂Ph₂)] readily undergoes insertion of [M(PR₃)₂] fragments (M = Pd, Pt) to give complexes in which phosphorus bridges two different metal atoms.

Keywords

PHOSPHORUS
MOLECULAR STRUCTURE

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Novel insertion of [M(PR3)2] fragments (M = Pd, Pt) into the strained phosphorus–carbon bond of the phosphirene complex [W(CO)5(PhPC2Ph2)]. Crystal and molecular structure of [PtW(CO)5(PEt3)2(PhPC2Ph2)]

Abstract

Keywords

Novel insertion of [M(PR₃)₂] fragments (M = Pd, Pt) into the strained phosphorus–carbon bond of the phosphirene complex [W(CO)₅(PhPC₂Ph₂)]. Crystal and molecular structure of [PtW(CO)₅(PEt₃)₂(PhPC₂Ph₂)]