Reductive ring opening of thiazoles
- 1 January 1974
- journal article
- research article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 93 (1) , 18-20
- https://doi.org/10.1002/recl.19740930109
Abstract
The course of the reductive ring‐opening reactions of 2‐mercapto‐, 2‐hydroxy, 2‐amino‐, 2‐methylamino‐ and 2‐dimethylamino‐4‐methylthiazoles with sodium in liquid ammonia, yielding substituted propenethiolates, has been found to depend on the nature of the hetero substituent. The mechanism of the ring opening is discussed.Keywords
This publication has 6 references indexed in Scilit:
- Chemistry of acetamidoalkenethiolates III. Synthesis of substituted 1,4,2‐oxathiazines and 1,3,4‐thiadiazinesRecueil des Travaux Chimiques des Pays-Bas, 1973
- Chemistry of alkenethiolates. Six- and seven-membered rings with two hetero atomsRecueil des Travaux Chimiques des Pays-Bas, 1973
- New reactive intermediates from carbon‐sulfur bond cleavage in heterocyclic compoundsRecueil des Travaux Chimiques des Pays-Bas, 1973
- 195. Chemistry of micrococcin P. Part IV. A method for the structural study of thiazolesJournal of the Chemical Society, 1960
- Preparation of Secondary and Tertiary 2-ThiazolylaminesJournal of the American Chemical Society, 1952
- Über die Oxy‐thiazole oder ThiazoloneBerichte der deutschen chemischen Gesellschaft (A and B Series), 1927