Absolute stereochemistry of chinesin I and II
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 6,p. 683-688
- https://doi.org/10.1039/p19950000683
Abstract
The absolute stereochemistry of chinesin I and II has been elucidated by synthetic and spectroscopic experiments. Tetrahydrochinesin I was degraded with ozonolysis and converted into the cyclopentane derivative 5 whose absolute stereochemistry was elucidated by synthesis from (–)-linalool. Degradation of chinesin I with H2SO4 gave (S)-2-methylbutyric acid. Finally, the absolute configuration of chinesin I was established as 4R, 8S, 9R, 12R, 24S.Keywords
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