Extremely High Enantiomer Recognition in HPLC Separation of Racemic 2-(Benzylsulfinyl)benzamide Using Cellulose Tris(3,5-dichlorophenylcarbamate) as a Chiral Stationary Phase
- 1 October 2000
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 29 (10) , 1176-1177
- https://doi.org/10.1246/cl.2000.1176
Abstract
An extremely high enantioselectivity of cellulose tris(3,5-dichlorophenylcarbamate) was found when it was used as a chiral stationary phase (CSP) in high-performance liquid chromatography (HPLC). The enantioseparation factor (α = 112) reported in this system for 2-(benzylsulfinyl)benzamide seems to be the highest among many enantiomer-differentiating separations using polysaccharide derivatives as CSPs.Keywords
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