Asymmetric, redox-active carbonyl complexes with [Rh2]2+, [Rh2]3+, and [Rh2]4+ cores
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 246-248
- https://doi.org/10.1039/c39870000246
Abstract
The [Rh2]2+ complex [Rh2(CO)2(bipy)(µ-RNNNR)2](2, bipy = 2,2′-bipyridyl, R =p-tolyl) is the precursor to asymmetric, redox-active [Rh2]3+ and [Rh2]4+ derivatives such as [Rh2(CO)L(bipy)(µ-RNNNR)2]z(3+, L = PPh3, z= 1; 4, L = I, z= 0) and [Rh2(CO)(S2CNMe2)(piby)(µ-RNNNR)2][PF6](5) respectively.Keywords
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