A semiclassical approximation to quantum dynamics
- 1 November 1979
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 71 (9) , 3880-3885
- https://doi.org/10.1063/1.438797
Abstract
In this paper we advance a new approximation scheme for the dynamics of an N particle system, which is based on the expansion of the Heisenberg equations of motion in powers of h/ in the coherent state representation. The time evolution of the physical observables is generated classically by a Hamiltonian Hs, which is derived from the original Hamiltonian by adding 2N2 virtual particles to the system. These virtual particles are related to the dispersion of the quantum mechanical wave function, and reflect the (time dependent) sensitivity of the instantaneous positions and momenta xi, pi to the variation of the initial conditions. The approximate equations of motion preserve the commutation relations between the coordinates and the momenta and the total (quantum) energy. The present approximation may be adequate for the study of the dynamics of coupled anharmonic oscillators in the quasiperiodic regime.Keywords
This publication has 48 references indexed in Scilit:
- New phenomenon in the stochastic transition of coupled oscillatorsPhysical Review A, 1978
- Stochastic transition in the unequal-mass Toda latticePhysical Review A, 1975
- A direct method for modifying certain phase-integral approximations of arbitrary orderAnnals of Physics, 1974
- Classical S-Matrix for Vibrational Excitation of H2 by Collision with He in Three DimensionsThe Journal of Chemical Physics, 1972
- Classical S Matrix for Linear Reactive Collisions of H+Cl2The Journal of Chemical Physics, 1971
- Stochastic Behavior of Resonant Nearly Linear Oscillator Systems in the Limit of Zero Nonlinear CouplingPhysical Review A, 1970
- Phase-Integral Approximation in Momentum Space and the Bound States of an Atom. IIJournal of Mathematical Physics, 1969
- Phase-Integral Approximation in Momentum Space and the Bound States of an AtomJournal of Mathematical Physics, 1967
- Coherent and Incoherent States of the Radiation FieldPhysical Review B, 1963
- Semiclassical description of scatteringAnnals of Physics, 1959