Synthesis of novel axially chiral Rh–NHC complexes derived from BINAM and application in the enantioselective hydrosilylation of methyl ketones
- 17 October 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 23,p. 2916-2917
- https://doi.org/10.1039/b309185f
Abstract
Novel axially chiral Rh N-heterocyclic carbene complexes were prepared from axially dissymmetric 1,1′-binaphthalenyl-2,2′-diamine and applied in the Rh-catalyzed enantioselective hydrosilylation of methyl ketones. The corresponding sec-alcohols can be obtained in high yields with good to excellent ee.Keywords
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