The role of internal ligand modes in promoting radiationless transitions in metal complexes
- 1 November 1978
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 36 (5) , 1321-1327
- https://doi.org/10.1080/00268977800102371
Abstract
The effect of internal ligand modes on the radiationless relaxation in metal complexes is considered. The theoretical model of the process is formulated within the framework of a dynamic coupling mechanism. The non-radiative rate constant is given as a product of an electronic and a vibrational factor, and it is concluded that it is the electronic factor that is rate-determining.Keywords
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