Zeolite-entrapped osmium carbonyl clusters: selective and stable catalysts for CO hydrogenation
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 347-349
- https://doi.org/10.1039/c39890000347
Abstract
[H2Os(CO)4] is converted in the pores of a basic form of zeolite Y (formed by treatment with NaN3)to give entrapped Os carbonyl clusters that catalyse CO hydrogenation at 573 K and 19 bar (1 bar = 105 Pa) to give C2—C4 hydrocarbons in high yield with only slow loss of catalytic activity and selectivity.Keywords
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