Studies on the Decomposition of Tetra-alkylammonium Salts in Solution. V. Rates and Activation Parameters of Salts Containing Substituted-benzyl or Other Active Groups
- 1 May 1972
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 50 (9) , 1297-1302
- https://doi.org/10.1139/v72-203
Abstract
First order rate constants and activation parameters are reported for the decomposition in chloroform and acetone solvents of a series of 4-substituted-benzylphenyldimethylammonium bromides and iodides and also of a series of tetra-alkylammonium bromides which contain no benzyl group. The results are discussed in terms of general mechanism of these reactions, which are unimolecular "ionic internal" nucleophilic substitutionsKeywords
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