Synthesis of the carbido cluster [Os10(CO)24C]2? and the X-ray structure of [Os10(CO)24C][(Ph3P)2N]2
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 224-226
- https://doi.org/10.1039/c39800000224
Abstract
The carbido dianion [Os10(CO)24C]2– has been isolated from the pyrolysis of Os3(CO)11(py)(py = pyridine), and the pyrolysis of Os3(CO)12; an X-ray structural analysis of the [(Ph3P)2N]+ salt has shown a tetrahedral arrangement of ten metal atoms that is a fragment of a cubic close packed array.Keywords
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