Stability of the metal–carbon–halogen system. Part I. The preparation and properties of some platinum(II)- and palladium(II)-vinyl complexes
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 1,p. 34-40
- https://doi.org/10.1039/dt9740000034
Abstract
A number of chlorovinyl complexes of palladium and platinum have been prepared from the reaction of the zerovalent palladium or platinum complexes [(Ph3P)4M] with chlorinated olefins such as tetrachloroethylene, trichloroethylene, and dichloroethylene. 1H N.m.r. spectroscopic studies of the complexes containing PPh2Me have allowed the stereochemistry of the new compounds to be established. Oxidation of the PtII complexes with chlorine yields six-co-ordinate vinyl complexes of PtIV.Keywords
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