[PtCl3(C2H4)]-[(S,S)-(PhMeCH)2NH2]+: A New and Versatile Ionic Organometallic Chiral Derivatizing Agent for the Determination of the Enantiomeric Composition of Chiral Unsaturated Compounds by 195Pt NMR Spectroscopy
- 1 June 2000
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 2 (13) , 1795-1798
- https://doi.org/10.1021/ol0000509
Abstract
The ionic complex [PtCl3(C2H4)]-[(S,S)-(PhMeCH)2NH2]+ containing a chiral secondary amine is a new and versatile chiral derivatizing agent (CDA) for the determination of the enantiomeric composition of several unsaturated compounds including simple olefins: the diastereoisomeric mixtures arising from the exchange of ethylene by the unsaturated analytes are easily detected by 195Pt NMR spectroscopy.Keywords
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