Deprotonation and anionic rearrangements of organometallic compounds. Reactions of the hydride complex (η5-C5H5)Re(NO)(PPh3)(H) with n-butyl-lithium–tetramethylethylenediamine
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 283-284
- https://doi.org/10.1039/c39850000283
Abstract
The title reaction (–71 °C; 1 h) gives (η5-C5H4Li)Re(NO)(PPh3)(H)(8), which subsequently rearranges intramolecularly (–32 °C; 0.5 h) to give Li+[(η5-C5H5)Re(NO)(PPh3)]–(3); the anions (8) and (3) are characterized by reaction with electrophiles.Keywords
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