Zur Chemie des 1-Aza-2-bora-3-oxacyclopentansystems / The Chemistry of the 1-Aza-2-bora-3-oxacyclopentane System
Open Access
- 1 April 1980
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 35 (4) , 447-453
- https://doi.org/10.1515/znb-1980-0407
Abstract
Derivatives of 1-aza-2-bora-3-oxacyclopentane are easily prepared by cleavage of the N-Si and O-Si bonds in disilylated ethanolamines with halogenoboranes. The B-halogeno and B-hydro compounds with NH and N-CH3 moieties are associated in the solid state, and in part also in the liquid and gas phase. In the solid phase hexahydroborazine derivatives are formed by association. Further compounds include B-N-Si-substituted rings and interlinked bicyclic systems.Keywords
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