The enantiocontrolled synthesis of (–)-tricholomenyn A, a novel antimitotic enynylcyclohexenone from Tricholoma acerbum
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 14,p. 1679-1680
- https://doi.org/10.1039/cc9960001679
Abstract
(–)-Tricholomenyn A, a structurally novel antimitotic enynylcyclohexenone from Tricholoma acerbum, is synthesized in an enantiocontrolled manner from a chiral synthon of cis-1,4-dihydroxycyclohexa-2,5-diene and verifies the relative and the absolute structures of the natural product.Keywords
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