Stereoselective synthesis of chiral coordination polymers with partial control of the rigid main chain topology
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 24,p. 2529-2530
- https://doi.org/10.1039/a906645d
Abstract
The condensation polymerization between the appropriate enantiomers of [Ru(1,10-phenanthroline-5,6-dione)2- (bpy)]2+ 1 and [Ru(1,10-phenanthroline-5,6-diamine)2- (bpy)]2+ 2 in meta-cresol gave the homochiral coordination polymers Δ-3 and Λ-3 as well as the meso polymer, ΔΛ-3, which exhibit rigid, ribbon-like structures with different main chain topologies.Keywords
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