NMR Studies of Inorganic Fluorides. I. High‐Resolution 19F Spectra of Si2F6 and (SiF3)2O
- 1 February 1966
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 44 (3) , 962-964
- https://doi.org/10.1063/1.1726849
Abstract
Fluorine NMRspectra of hexafluorodisilane and hexafluorodisiloxane have been recorded and analyzed. The 19F–19F and 29Si–19F spin coupling constants were obtained from the satellite spectra arising from the 29Si‐substituted molecules present in natural abundance. The ``near'' and ``far'' 29Si–19F coupling constants in Si2F6 were found to be of opposite sign.Keywords
This publication has 13 references indexed in Scilit:
- Relative Signs of the Nuclear Spin Coupling Constants in Propylene Oxide and Indene OxideThe Journal of Chemical Physics, 1965
- Analysis of NMR Spectra by Least SquaresThe Journal of Chemical Physics, 1964
- Silicon-Crystal Determination of the Absolute Scale of X-Ray WavelengthsPhysical Review B, 1964
- The N.M.R. spectra of the A3*A3*X2and the A4X2systemsMolecular Physics, 1963
- FLUORINE N.M.R. SPECTROSCOPY. XI. CCl2F-CCl2F; PROOF OF OPPOSITE SIGNS FOR J(C13F) AND J(C13CF) BY SPIN DECOUPLINGThe Journal of Physical Chemistry, 1963
- Use of Weak Perturbing Radio-Frequency Fields in Nuclear Magnetic Double ResonanceThe Journal of Chemical Physics, 1962
- High-Resolutjon nuclear-magnetic-resonance spectra of hydrocarbon groupings VI. The hydrogen spectra of carbon-13 substituted ethane, ethylene and acetyleneProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1962
- Analysis of Complex NMR Spectra. An Iterative MethodThe Journal of Chemical Physics, 1962
- The Fluorination of Chlorodisiloxane. Silicon Oxyfluoride1Journal of the American Chemical Society, 1945
- HEXAFLUORODISILANE1Journal of the American Chemical Society, 1932