Cycloaddition reaction of tert-butyl isocyanate and a tellurium diimide dimer: extended helical structure of the ureato telluroxide {[OC(μ-NBut)2TeO]2(thf)}∞

Abstract
The reaction of ButNTe(μ-NBut)2TeNBut with ButNCO in a 1∶4 molar ratio in thf produces N,N′-bis(tert-butyl)ureato telluroxide dimers [OC(μ-NBut)2TeO]2, which form an extended helical network via weak CO⋯Te interactions.

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