A novel quinquedentate N5 macrocycle containing a pendant amino group
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 192-193
- https://doi.org/10.1039/c39850000192
Abstract
The addition of the monoanion of nitromethane to the CN group of [Ni(C-rac.-N-meso-2,5,10,12-tetramehtyl-1,4,8,11-tetra-azacyclotetradeca-4,11-diene)][ClO4]2(1) followed by reduction gives the nickel(II) complex (4), containing the pendant -CH2NH2 group; the free ligand (5) may be obtained by treating the nickel complex with dry HCl gas in acetonitrile solution.Keywords
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