Molecular ion source having low energy spread and single-electron-impact excitation

Abstract
A cylindrically symmetric electron-bombardment ion source is described that has been useful in beam experiments with molecular ions. Measurements indicate that the ions have a kinetic-energy spread (full-width at half-maximum) of 0.5–1.0 eV, a current of several microamperes, and a population distribution that is consistent with vibrational and rotational factors resulting from single-electron-impact ionization. The source exhibits low noise (≲ twice the theoretical shot-noise limit) and has a compact and easily serviceable construction.