NUCLEAR MAGNETIC RESONANCE STUDY OF EXCHANGING SYSTEMS. VI. ROTATIONAL BARRIER OF FORMANILIDE BY 13C NMR COMPLETE LINE SHAPE ANALYSIS
- 5 June 1974
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 3 (6) , 521-524
- https://doi.org/10.1246/cl.1974.521
Abstract
The complete line shape analysis of temperature-dependent 13C NMR spectra of formanilide in the system where the populations of the isomers change with temperature was performed by a modified Bloch equation method, and the activation parameters of the restricted rotation around amide bond were determined accurately.Keywords
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