Reduction of co-ordinated carbon dioxide to carbon monoxide via protonation by thiols and other Brønsted acids promoted by Ni-systems: a contribution to the understanding of the mode of action of the enzyme carbon monoxide dehydrogenase
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 450-452
- https://doi.org/10.1039/c39880000450
Abstract
Carbon dioxide co-ordinated to Ni0 is easily reduced to bound carbon monoxide by R–SH (R = H, alkyl, benzyl, phenyl, and substituted phenyl) and other Brønsted acids, providing a reasonable model for the Ni-containing enzyme carbon monoxide dehydrogenase.Keywords
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