Solvothermal synthesis and crystal structure of [NEt4]6[ {Mo3(μ3-Se)(μ-η2-Se 2)3(η2-Se2)(μ-η 2-Se5)(η1-Se5)} 2(μ-η2-Se4)]. The first trinuclear molybdenum polyselenide dimer containing two [Mo3Se7]4+ cluster cores bridged by a Se42− chain
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 5,p. 709-710
- https://doi.org/10.1039/a608185a
Abstract
Two equivalent [Mo 3 Se 19 ] 2- moieties, each composed of a [Mo 3 Se 7 ] 4+ cluster core, two ligating Se 5 2- chains and a (η 2 -Se 2 ) 2- group, are bridged by a Se 4 2- chain to form the [Mo 6 Se 42 ] 6- ion.Keywords
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