Stereochemistry and mechanism of the nickel-catalysed hydrocyanation of conjugated dienes
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 260-261
- https://doi.org/10.1039/c39840000260
Abstract
Nickel-catalysed addition of deuterium cyanide to cyclohedxa-1,3-diene was shown to occur with cis stereochemistry, indicating that a cis-migration of co-ordinated cyanide takes place in an intermediate π-allylnickel complex.Keywords
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