Polynuclear nickel(II) complexes of N4O2- and N4S2-compartmental macrocycles: the structures of a Ni4O4cubane cluster and the binuclear nickel(II) complex of a benzenethiolate macrocycle
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1662-1665
- https://doi.org/10.1039/c39930001662
Abstract
The tetranuclear cluster [{Ni2(L1)(MeCO2)}2]2+(L1= the dianion of the condensation product of 1,3-diaminopropane and 2,6-diformyl-4-methylphenol) shows a distorted Ni4O4cubane structure consisting of octahedral nickel(II) centre; the structure of the dithiolate analogue [Ni2(L2)](PF6)2·2dmf (L2= the dianion of the condensation product of 1,3- diaminopropane and 2,6-diformyl-4-methylbenzenethiol;dmf = dimethylformamide)shows square-planar coordination at nickel(II).Keywords
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