Vitamin D (calciferol) and its analogs. 20. Synthesis of 3-deoxy-3,3-dimethyl-1-hydroxyvitamin D3 from vinylallene intermediates and related thermal and configurational studies
- 1 September 1980
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 45 (20) , 4015-4020
- https://doi.org/10.1021/jo01308a014
Abstract
No abstract availableThis publication has 7 references indexed in Scilit:
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- Two new vitamin D isomers. Formation of (3S,10R)-(Z,Z)-9,10-secocholesta-5,7,14-trien-3-ol and its 10S-epimer from cis-isotachysterol3 via facile [1,7]sigmatropic rearrangementsThe Journal of Organic Chemistry, 1978
- Studies on vitamin D (calciferol) and its analogs. 13. 3-Deoxy-3.alpha.-methyl-1.alpha.-hydroxyvitamin D3, 3-deoxy-3.alpha.-methyl-1.alpha.,25-dihydroxyvitamin D3, and 1.alpha.-hydroxy-3-epivitamin D3. Analogs with conformationally biased a ringsThe Journal of Organic Chemistry, 1978
- Reaction of copper enolates of esters with propargylic systems. Facile preparation of 3,4-dienoic esters, stereoselective rearrangement to (2E,4Z)- and (2E,4E)-dienoic esters, and stereoselective synthesis of a fragrance from the Bartlett pearThe Journal of Organic Chemistry, 1978
- Conformational analysis of vitamin D and analogs. 1. Carbon-13 and proton nuclear magnetic resonance studyThe Journal of Organic Chemistry, 1977
- Synthesis and bioassay of 3-deoxy-1α-hydroxyvitamin D3, an active analog of 1α,25-dihydroxyvitamin D3Bioorganic Chemistry, 1977