Thiol exchange reactions of iron–molybdenum–sulphur clusters; preparation and X-ray crystal structure of [Et4N]3[Fe6Mo2S8(SCH2CH2OH)9], a water soluble iron–molybdenum–sulphur cluster
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 91-93
- https://doi.org/10.1039/c39790000091
Abstract
Complete thiolato-ligand exchange has been demonstrated for [Fe6Mo2S8(SR)9]3–(R = alkyl) complexes and used to prepare the water-soluble 2-hydroxyethanethiolato-derivative which has been structurally characterised as its [Et4N]+ salt; the complex is stable in buffered aqueous solution, in the presence of an excess of 2-hydroxyethanethiol, and in the absence of dioxygen.Keywords
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