Electric Dipole Moments of Several Molecules from the Stark Effect
- 1 February 1953
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 21 (2) , 308-310
- https://doi.org/10.1063/1.1698877
Abstract
The following molecular electric dipole moments, in Debye units, have been obtained from the Stark effect of pure rotational spectra observed in the microwave region: 0.234±0.004 for NF3; 1.03±0.01 for PF3; 1.77±0.02 for POF3; 3.00±0.02 for HCN; 3.92±0.06 for CH3CN; 3.83±0.06 for CH3NC; 1.79±0.02 for CH3F; 0.75±0.01 for CH3CCH; 1.26±0.01 for SiF3H. All values apply to the ground vibrational state.Keywords
This publication has 7 references indexed in Scilit:
- Microwave Spectra and Molecular Constants of Trifluorosilane Derivatives. SiH, SiC, SiCl, and SiBrPhysical Review B, 1950
- Molecular Dipole Moments and Stark Effects. II. Stark Effects in OCSPhysical Review B, 1950
- A Stark-Effect Microwave Spectrograph of High SensitivityReview of Scientific Instruments, 1949
- Rotational Absorption Spectrum of OCSPhysical Review B, 1949
- Electric quadrupole coupling of the nuclear spin with the rotation of a polar diatomic molecule in an external electric fieldJournal of Research of the National Bureau of Standards, 1948
- Bond Distances in OCS from Microwave Absorption LinesPhysical Review B, 1947
- The dipole moment of the C—H bondTransactions of the Faraday Society, 1942